What is intergranular stress corrosion cracking igscc. A team of researchers exploring the intergranular stress corrosion cracking of a type of metallic tubing used within nuclear power plants has developed a technique to both map and predict its. Stresscorrosion cracking, materials performance and. Intergranular stress corrosion cracking igscc of bwr internal components has been identified as a technical issue of concern by both the nrc staff and the industry.
Good practices and lessons learned international atomic energy agency vienna isbn 978920. Prediction of stress corrosion cracking scc in nuclear. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Stress stress, evidenced by cracking, is caused by the simultaneous effects of tensile stress and corrosion. Feb 06, 2011 many stress related failures are associated with. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. At 3 dpa, transgranular cracking was negligible, and fracture surface was either dominantly intergranular, as in fieldcracked core internals, or dominantly ductile or mixed. Intergranular corrosion or intergranular cracking was occurred on the surface of pdeoxidized 12h and o copper tubes under gasphase ammonia. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Setup and results of a grain scale model of intergranular cracking. The chloride concentration in the solution leads to localized pitting or crevice corrosion nucleation. Stress corrosion cracking can proceed in one of two ways. Intergranular stress corrosion cracking igscc is stress corrosion cracking where the grain boundaries of a susceptible material are cracked due to stress and an agressive environment.
Stress corrosion cracking international institute of. The igc and scc susceptibility of aa5182 was found to depend strongly on sensitisation heat treatments. Fox and chemaxx experts are available to assist in all aspects of chemicalrelated accidents, fires, explosions, metallurgy, corrosion and failure analysis. Intergranular stress corrosion cracking an overview. The iaea nuclear energy series complements the iaea safety standards. Discussion caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et al. For stress corrosion cracking to occur in a weldment three conditions must be simultaneously present. This paper evaluates the resistance to intergranular stresscorrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. This paper evaluates the resistance to intergranular stress corrosion cracking igscc in the boiling water reactor of several grades and compositions of austenitic stainless steel castings. A combination of scc and iga has been observed in alloy 600 tubing on the hot leg of some operating steam generators in pressurized water reactor pwr nuclear power plants, and sodium hydroxide along with several other chemical species have. Mechanisms of stress corrosion cracking and intergranular.
Intergranular corrosion and stress corrosion cracking of. An overview of intergranular stress corrosion cracking in. Inter granular corrosion can be detected by ultrasonic and eddy current methods. This post will cover essential information about two forms of corrosion chosen by me, that are intergranular corrosion and stress corrosion. Nuclear corrosion science and engineering 1st edition. In the literature it is a common belief that electropolishing mitigates primary water stress corrosion cracking pwscc because it removes superficial cold work. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Igscc stands for intergranular stress corrosion cracking also intergranular stress corrosion cracking and 2 more what is the abbreviation for intergranular stress corrosion cracking.
Xray diffraction technique maps strain, crack propagation. The mechanism of cracking in both these modes and the conditions under which the transition from tram to intergranular cracking or vice versa occur are topics of much debate and research, some recent work have suggested that the mechanism of trans and intergranular stress corrosion cracking are identical, in this study, by using the load. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion. The scope of the programme included inservice inspection, assessment. Timetofailure tests and crackgrowthrate tests are widespread practices for studying the response of various materials undergoing scc. Intergranular stress corrosion cracking of welded steel twi. Intergranular stress corrosion cracking igscc has long been an issue of serious concern in the pipeline industry. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be susceptible to intergranular corrosion or intergranular stress corrosion cracking. The simultaneous occurrence of three conditions are essential for the igscc in bwrs. Intergranular stress corrosion cracking is common in alloys that are otherwise typically corrosionresistant.
Intergranular corrosion facts and how to reduce the risk. The company has at its disposal stateoftheart scientific investigative techniques as well as conventional analytical methods and mechanical testing. Elsevier journal of nuclear materials 216 1994 326347 effects of irradiation on intergranular stress corrosion cracking g. Intergranular corrosion is localized attack along the grain boundaries, or immediately adjacent to grain boundaries, while the bulk of the grains remain largely unaffected.
Mechanistic differences in transgranular and intergranular. Intergranular corrosion intergranular corrosion is an attack on the grain boundaries of some alloys under specific. The flixborough explosion was the largestever peacetime explosion in the uk. This behavior indicates that percent intergranular stress corrosion cracking determined at. Here, it is shown that electropolished alloy 600 uns n06600 exposed to hydrogenated steam undergoes internal cr oxidation, whereas mechanical polishing induces external oxidation. Iaea nuclear energy series technical reports stress corrosion cracking in light water reactors. Those pictures show that the weld nugget is sensitive to pitting corrosion when it is not submitted to a mechanical loading gure 3a. Intergranular corrosion degradation and surface engineering. Transgranular stress corrosion cracking tgscc is the same as igscc, but the grain boundaries are not preferentially attacked 1, 2. Strauss, huey and streicher are the common test methods. The core shroud is among the list of internals susceptible to igscc. Stress corrosion cracking of piping materials may have serious consequences on safety as well as on the economy of a nuclear plant.
Effects of irradiation on intergranular stress corrosion. A specific objective of this work was to predict the performance of alloy casting institute cf3, cf3a, and cf8 castings in nuclear applications. Irradiationinduced stress corrosion cracking of austenitic. Intergranular stress corrosion cracking tends to occur when preexisting inter granular fractures are present. Effects of irradiation on intergranular stress corrosion cracking. In recent years, several studies have been conducted on the intergranular stress corrosion cracking scc and intergranular attack iga of alloy 600. Bruemmer b a departments of nuclear engineering and materials science and engineering, university of michigan, ann arbor, mi 48109, usa.
This overview paper discusses each essential condition and the remedies for igscc that modify each condition. Abstract susceptibility to intergranular attack iga and intergranular stress corrosion cracking igscc of alloy 690 uns n06690 was investigated using chemical etching, doubleloop electrochemical potentiokinetic reactivation dlepr, and slow. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. Intergranular stress corrosion cracking scc of pipelines has been known to cause pipeline failure since the 1960s and is associated with a high ph, above 9, in the electrolyte in direct contact with the external pipe surface. Stress corrosion cracking of chemical reactor the flixborough explosion, uk 1974.
Intergranular stress corrosion cracking ion exchange labeling chemicals mapp gas cylinders material safety data sheets metallurgy methane methanol methylene chloride model car fire mtbe natural gas nfpa codes 921, 54, 58, etc. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Results of these activities were a basis for the formulation of the objective and scope of the extrabudgetary programme on mitigation of intergranular stress corrosion cracking in rbmk reactors the programme. Natesan nuclear engineering division argonne national laboratory argonne, il 60439 june 2012 work sponsored by the u. A new understanding of intergranular stress corrosion. Mod01 lec27 pitting corrosion, intergranular corrosion duration. Despite the fact that several catastrophic failures have been reported so far due to this reason all over the world in the last forty years or so see, e. Chloride induced stress corrosion cracking ciscc of spent nuclear fuel storage canisters is a serious concern since it can potentially lead unexpected premature failure of the canisters. Why is chloride stress corrosion cracking transgranular. The list of acronyms and abbreviations related to igscc intergranular stress corrosion cracking. May 10, 2016 at 3 dpa, transgranular cracking was negligible, and fracture surface was either dominantly intergranular, as in fieldcracked core internals, or dominantly ductile or mixed.
An overview of intergranular stress corrosion cracking igscc in boiling water reactors bwrs is presented. Intergranular stress corrosion cracking of copper a case. A major challenge faced in their maintenance is to identify the ways to assess two types of phenomena related to corrosionstress corrosion cracking and activity buildup, or the buildup of activated corrosion products onto the reactor cooling system surfaces. They are carried out as a rule on samples from finished tubes in the asdelivered condition or on material that has been sensitized, i. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 11. Intergranular corrosion igc testing is the only corrosion test performed as a standardized predelivery test.
There were 28 fatalities as well as the near complete destruction of the nypro plant in north lincolnshire by blast and then fire. Sensitization, intergranular attack, stress corrosion. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Characterization of intergranular stress corrosion. This overview paper discusses each essential condition and the remedies for igscc. This form of scc is found on pipelines with cathodic protection that is less than optimum, i. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Jan 22, 2014 a team of researchers exploring the intergranular stress corrosion cracking of a type of metallic tubing used within nuclear power plants has developed a technique to both map and predict its. Effect of surface preparation on intergranular stress. Intergranular stress corrosion cracking igscc is a mode of subcritical crack propagation in susceptible nickelbased alloys and austenitic stainless steels used in power generation. Intergranular stress corrosion cracking igscc is more common than transgranular scc. Intergranular cracking proceeds along the grain boundaries whereas transgranular cracking does not have preferences for boundaries 69.
This form of corrosion is usually associated with chemical segregation effects impurities have a tendency to be enriched at grain boundaries or specific phases. A combination of scc and iga has been observed in alloy 600 tubing on the hot leg of some operating steam generators in pressurized water reactor pwr nuclear power plants, and sodium hydroxide along with. A major challenge faced in their maintenance is to identify the ways to assess two types of phenomena related to corrosionstress corrosion cracking and activity buildup, or the buildup of activated corrosion products onto the reactor cooling. Jun 05, 2017 mod01 lec27 pitting corrosion, intergranular corrosion duration. Nuclear power osha oxidizers oxygen p2s5 packaging chemicals packaging food paint. Oct 23, 2014 this post will cover essential information about two forms of corrosion chosen by me, that are intergranular corrosion and stress corrosion. May 22, 2015 united states nuclear regulatory commission office of nuclear reactor regulation washington, d. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized. Intergranular stress corrosion crack propagation in hot. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Stress corrosion cracking scc is a significant ageing degradation mechanism for major components of both pressurized water reactors pwrs and boiling water reactors bwrs. In the case of transgranular scc, the cracks advanced across the specific crystal planes with low indices 70. Stress corrosion cracking scc is a very common failure mechanism characterized by a slow, environmentally induced crack propagation in structural components. Secondary cracking branching was evident in both the transgranular and intergranular regions, though secondary cracking in the intergranular regions was more extensive.
Intergranular stress corrosion cracking resistance of. Radiation damage is the effect of ionizing radiation on physical objects. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing conditions in the water. Irradiationassisted stress corrosion cracking behavior. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Intergranular corrosion what is intergranular corrosion. The catastrophic explosion at flixborough in june 1974 has been traced to. A computational model for intergranular stress corrosion cracking.
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